WebJul 13, 2024 · 1 INTRODUCTION. Thioxanthone 1 is a popular triplet sensitizer in photoinitiated reactions because of its high molar absorptivity in the near-UV spectral … WebAug 10, 2024 · As shown in Schemes 1.3 and 1.4, photoreaction of thioxanthone derivatives with amines generates ketyl radicals (e.g. 14 and 16) and α-aminoalkyl radicals (15) or amino radicals (17).Radicals 15 and 17 are able to add efficiently to olefinic monomers, such as acrylates, to initiate polymerization. However, the thioxanthone ketyl radicals (e.g. 14 …
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